Beilstein J. Org. Chem.2014,10, 936–947, doi:10.3762/bjoc.10.92
transfer; kinetic; photocatalysis; photochemistry; photocyclic initiating system; photopolymerization; photoredox catalysis; radicalgenerator; Introduction
Among the possible usage of light, the conversion of photons into chemical energy, as stored into radicals or ions, is of great interest. As a part
), high radical production (>10−3 M). But these studies also reveal the importance of component choice: great care must be taken in order to build photocatalytic radicalgenerator by combination of three compounds. Especially a simple thermodynamic approach should help to select the candidates as a